Bis(cobaltocenium) tetrachloridocobaltate(II) dichloromethane 1.2-solvate
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چکیده
منابع مشابه
[μ-Bis(diphenylphosphanyl-κP)methane]decacarbonyltri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
In the title compound, [Re(3)(μ-H)(3)(C(25)H(22)P(2))(CO)(10)]·CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis-(diphenyl-phosphan-yl)methane ligand bridges two Re atoms. Neglecting the Re-Re inter-actions, each Re atom is in a slightly distorted octa-hedral coordination environment. The dichloro-methane solvent mol-ec...
متن کاملCrystal structure of trans-(dicyano)bis(triphenylphosphine)palladium(II) dichloromethane solvate.
was obtained from the reaction of Pd(PPh3)4 with Me3SiCN (1:1 molar ratio) in benzene (at 80 ̊C for 2 h). Crystals suitable for X-ray diffraction analysis were obtained by recrystallization from a mixture of CH2Cl2 and C6H6 (ca. 1:4 by volume). Table 1 summarizes the crystal and experimental data. During the data collection at room temperature, decay was not observed. All intensity data were cor...
متن کاملDichlorido(9-methyladenine-κN 7)(η5-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate
In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN(7))]·CH(2)Cl(2) (9-MeAde = 9-methyl-adenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyl-adenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric...
متن کامل12-Ethoxy-2,3,8,9-tetramethoxybenzo[c]phenanthridine dichloromethane solvate
The title compound, C(23)H(23)NO(5)·CH(2)Cl(2), was obtained via the alkyl-ation of the 12-hydr-oxy-2,3,8,9-tetra-methoxy-benzo[c]phenanthridine salt. The benzo[c]phenanthridine ring system is essentially planar, with a mean out-of-plane deviation of 0.026 Å. A dicloromethane mol-ecule of solvation is present and located between the sheets of phenanthridine mol-ecules, preventing any significan...
متن کاملDichloromethane Injection: Case Report
Background: Dichloromethane (a chlorinated hydrocarbon) is normally used as a solvent. Dichloromethane poisoning has been reported from occupational exposure and the common routes of dichloromethane poisoning are ingestion and inhalation. Case presentation: We described a case of 51-year-old man who received subcutaneous injection of dichloromethane and presented with local wound necrosis at hi...
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ژورنال
عنوان ژورنال: IUCrData
سال: 2018
ISSN: 2414-3146
DOI: 10.1107/s2414314618005527